Polarized nuclear target based on parahydrogen induced polarization
نویسندگان
چکیده
منابع مشابه
Parahydrogen-induced polarization at zero magnetic field.
We use symmetry arguments and simple model systems to describe the conversion of the singlet state of parahydrogen into an oscillating sample magnetization at zero magnetic field. During an initial period of free evolution governed by the scalar-coupling Hamiltonian HJ, the singlet state is converted into scalar spin order involving spins throughout the molecule. A short dc pulse along the z ax...
متن کاملTransfer of Parahydrogen-Induced Polarization to 19F:
Introduction Parahydrogen-Induced Polarization (PHIP) leads to strong signal enhancement in H-NMR if unsaturated substrates are hydrogenated with parahydrogen (p-H2) applying an appropriate catalyst. As shown before, this polarization can be transferred to heteronuclei such as C. For imaging the lung, a F-hyperpolarized contrast agent should be available, if possible for inhalation. Normally, t...
متن کاملParahydrogen Induced polarization by homogeneous catalysis: theory and applications.
The alignment of the nuclear spins in parahydrogen can be transferred to other molecules by a homogeneously catalyzed hydrogenation reaction resulting in dramatically enhanced NMR signals. In this chapter we introduce the involved theoretical concepts by two different approaches: the well known, intuitive population approach and the more complex but more complete density operator formalism. Fur...
متن کاملParahydrogen induced polarization of barbituric acid derivatives: 1H hyperpolarization studies.
Homogeneous hydrogenation of barbituric acid derivatives with parahydrogen yields a substantial increase of the (1)H NMR signals of the reaction products. These physiologically relevant compounds were hydrogenated at both ambient and elevated temperatures and pressures using a standard cationic rhodium catalyst. The resulting nonthermal nuclear spin polarization (hyperpolarization) is limited b...
متن کاملMicrowave Induced Nuclear Polarization
The classical method to increase the nuclear spin polarization is the "solid effect" mainly developed by Abragam and Jeffries, where the Boltzmann polarization of unpaired electrons present in the sample is transferred to the nuclei by inducing forbidden transitions which flip one nucleus and one electron simultaneously (1,2). A different method is the optical nuclear polarization (ONP) which w...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment
سال: 2012
ISSN: 0168-9002
DOI: 10.1016/j.nima.2012.08.007